Product ID:C1680L, TF SOLVENT (LIQUID)
MSDS Date:06/01/1987
FSC:6850
NIIN:00N030049
MSDS Number: BPDML

CHEMTRONICS INC

8125 COBB CENTER DRIVE
KENNESAW, GA 30144
US

Emergency Phone: 404-424-4888

Info Phone: 404-424-4888

Preparer: S.H. STEIN

Cage: 2M589

CHEMTRONICS INC (CANCELLED USE 21267)

HAUPPAUGE, NY 11760 US

Telephone: 770-424-4888/800-645-5244

Cage: 2M589

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE;(FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM;1250 STEL

ACGIH TLV: 1000 PPM;1250 STEL

TO EPINEHPRINE IN LAB ANIMALS & COULD HAVE A

RTECS: 9999999ZZ

MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING

RTECS: 9999999ZZ

VOMIT AS THE HAZ OF ASPIR MATL INTO LUNGS IS

RTECS: 9999999ZZ

BECAUSE OF POSS INCR RISK OF

RTECS: 9999999ZZ

AS EPINEPHRINE, SHOULD BE CONSIDERED ONLY AS A LAST

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL RAT)43,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:VAP IS HEAVIER THAN AIR & CAN
CAUSE SUFFOCATION BY REDUCING O2 AVAILABLE FOR BREATHING. BREATHING
HIGH CONCENTRATIONS OF THESE PRODUCTS CAN CAUSE LIGHT-HEADEDNESS,
GIDDINESS, SHORTNESS OF BREATH , IRRITATION OF THE UPPER
RESPIRATORY PASSAGES AND MAY LEAD TO NARCOSIS, CARDIAC
IRREGULARITIES, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:UNCON OR DEATH. EYE:LIQ CNTCT CAN
CAUSE DISCOMFORT, USUALLY NO EXTENDED EFT. INGEST:LOW ORAL TOXICITY
BUT INGESTION SHOULD BE AVOIDED. SKIN:NOT CORROSIVE/IRRITANT AFTER
SINGLE CNTCT BUT RPTD LIQ CNTNR CAN CAUSE DEFAT OF SKIN RSLTGIN
IRRIT. MATL IS POORLY ABSORBED THRU SKIN. IN SCREENING TESTS WITH
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:MOVE TO FRESH AIR. CALL MD. IF NOT BRTHG, GIVE ARTF
RESP, PREF MOUTH-TO-MOUTH. IF BRTHG DFCLT, GIVE O2. DO NOT GIVE
EPINEPHRINE OR SIMILAR DRUGS. EYE:IMMED FLUSH W/PLENTY OF WATER FOR
AT LEAST 1 5 MINS. CALL MD. SKIN:FLUSH W/WATER. GET MD IF IRRIT
PRESENT. INGEST:NO SPECIFIC INTERVENTION IS INDICATED AS CMPD NOT
LIKELY TO BE HAZ BY INGEST. HOWEVER, CALL MD IF NEC. DO NOT INDUCE
(ING 4)

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING
FIRE CONDITIONS .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DECOMPOSITION MAY OCCUR. THERMAL
DECOMPOSITION PRODUCTS MAY INCULDE CHLORIDES, FLUORIDES AND
PHOSGENE .

Spill Release Procedures:VENTILATE AREA. REMOVE OPEN FLAMES OR RED HOT
SURFACES. ALLOW TO EVAPORATE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:USE ONLY IN WELL VENTILATED AREA.
AVOID BREATHING VAPORS AND PROLONGED SKIN EXPOSURE. DO NOT SPRAY ON
SKIN.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES AND
PHOSGENE .

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
NIOSH/MSHA APPROVED SCBA IS REQUIRED IF A LARGE SPILL OCCURS.
Ventilation:NORMAL VENT FOR STANDARD MFG PROC IS GEN ADEQ. LOC EXHSUT
SHOULD BE USED WHEN LGE AMTS RELD. MECH VENT IN LOW PLACES.
Protective Gloves:BUTYL GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH:NEUTRAL. HAZ DECOMP PRODS:& HYDROFLUORIC ACIDS & POSS CARBONYL
HALIDES. EFTS OF OVEREXP: EXPERIMENTAL ANIMALS, EXPOS AT APPROX
5,000 PPM (V/V)) & ABOVE, FOLLOWED BY LGE IV EPINEPHRINE CHALLENGE,
HA S INDUCED SERIOUS CARDIAC IRREGULARITIES. CHLOROFLUOROCARBON
(CFC) MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM (ING 2)

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Vapor Pres:334@ 77F
Vapor Density:6.5
pH:SUPDAT
Evaporation Rate & Reference:1.0 (EHTER=1)
Solubility in Water:0.2 @ 77F
Appearance and Odor:CLEAR WITH SLIGHT ETHEREAL ODOR

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:THIS CMPND CAN BE DECOMPOSED BY HIGH
TEMPS (OPEN FLAMES, GLOWING METAL SURFS, ETC.) FORMING HYDROCHLORIC
(SUPP DATA)

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE, AND LOCAL
REGULATIONS. RECLAIM BY DISTILLATION OR REMOVE TO PERMITTED WASTE
DISPOSAL FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.